Revealing Ammonia Quantification Minefield in Photo/Electrocatalysis

نویسندگان

چکیده

Photo/electrocatalytic ammonia synthesis has recently developed fast while the yields over state-of-the-art photo/electrocatalysts are still very moderate. Such low concentration of synthesized NH3 brings about a challenge to reliable quantification product in photo/electrocatalysis. Notably, we found that quantitative detection below 0.2 ppm is error-prone, which likely case happening majority photo/electrocatalytic synthesis, thus arising concerns rationality and accuracy for low-concentration these processes. Herein, discuss methodology used analyze reliability various methods trace aqueous media. The challenges facing photo/electrocatalysis can be overcome by integration with multiple methods. According data presented, also propose an effective criterion precise ammonia, avoiding unreasonable comparisons synthesis.

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ژورنال

عنوان ژورنال: Angewandte Chemie

سال: 2021

ISSN: ['1521-3773', '1433-7851', '0570-0833']

DOI: https://doi.org/10.1002/anie.202108769